Abstract
First iron(II) carboxylate cluster with the triangular metal core K[Fe3(μ3-OH)(OOCCMe3)6(HOOCCMe3)3] (I) has been isolated from the reaction between FeSO4·7H2O and KOOCCMe3 in the presence of the excess of pivalic acid in MeCN. The X-ray data and magnetic study show the complex molecular unit to be constructed of the Fe(II) atoms.
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