Abstract
Poly(ethylene terephthalate) is a widely used polymer in the blow molding bottles, electron industry, texiile industry and can be recycled to synthesize new materials such as polyurethane foam (PUf) and unsaturated polyester (UP). One of them, PUf has many desirable properties such as low thermal conductivity, low density, excellent dimensional stability, high strength-to-weight ratio, low moisture permeability and low water absorption. However, PUf is a highly flammable material. In this study, aluminum hydrogen phosphonate (AHP) was synthesized in order to investigate their flame retarding performances for PUf. UL-94 V-1 was obtained at 15 phr loading of AHP. The incorporation of flame retardant increased the fireresistant property of PUf. In addition, other properties such as density, foam structure, and water and moisture absorption were also investigated.
Highlights
Kh o sát h p thu n c: chu n b ba m u th cho m i v t li u v i ph ng pháp kh o sát theo tiêu chu n EN317 và ti n hành c t m u thành kh i h p vuông c nh 25±1mm, cho vào n c c t nhi t phòng
Fireproof behavior of polyurethane foam based on waste poly(ethylene terephthalate) using aluminum hydrogen phosphonate flame retardant
Summary
Hóa ch t c s d ng bao g m aluminum nitrate nonahydrate (Al(NO3)3.9H2O), ethylene glycol (EG), k m acetate dihydrate (Zn(Ac)2), natri hydroxide (NaOH) có xu t x t Trung Qu c, d u Silicone (Vi t Nam), methylene diphenyl diisocyanate (MDI, hàm l ng NCO 31,0%; nh t 210mPa.s, t tr ng 1,23kg/m3 25oC) s n xu t c. Hòa tan Al(NO3)3.9H2O vào n c và cho vào bình c u, khu y n khi dung d ch trong su t. Cho h n h p PET ph th i, EG, Zn(Ac) vào bình c u th y tinh ba c áy tròn gnvimt nhi t k , m t máy khu y c , và m t van x khí. Dung d ch qua l c l nh thu c bis(2-hydroxyethyl terephthalate) (BHET) k t tinh, r a l i nhi ulnvincl nh, s y khô s n ph m n kh i l ng không i. T o m u PUf/AHP un nóng h n h p BHET, silicone oil, n c thành dung d ch l ng, ti p t c cho ch t ch ng cháy AHP vào và khu ysbtohnhp ng nh t. Sau ó m u c gi trong t s y 60oC trong 24 gi
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