Abstract

Field desorption and surface diffusion of sodium on atomically clean germanium (100) and (111) single-crystal planes has been investigated by means of the field emission method. Sealed-off field emission tubes with a channel multiplier were used. The surface density of sodium adatoms on the germanium surface was determined by using a standard tungsten (112) crystal plane. The temperature dependence of the desorption field has been studied with the aim of determining the binding energy of sodium adatoms at zero coverage. The values of 1.83 ± 0.05 eV and 1.72 ± 0.05 eV were obtained for the germanium (100) and (111) planes, respectively. The correlation between the adsorbate and substrate properties and the properties of alkali adlayers on a semiconductor surface is discussed on the basis of experimental results.

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