Feasible synthesis of bifunctional polysilsesquioxane microspheres for robust adsorption of Hg(II) and Ag(I): Behavior and mechanism.

Abstract

The pollution of Hg(II) and Ag(I) to water system exerts hazardous effect to aquatic ecosystem and public security. Simple strategy for constructing adsorbents to efficient remove them is greatly desired. Thus, a series of thiol and amino groups containing bifunctional polysilsesquioxanes (ASPSS) microspheres with adjustable porous structure and functional group content were synthesized by one-step feasible sol-gel process. The adsorption behavior and mechanism of ASPSS microspheres toward Hg(II) and Ag(I) was thoroughly determined. The maximum adsorption capacity of ASPSS for Hg(II) and Ag(I) are 4.32 and 3.86mmol·g-1 under 25℃. The as-prepared ASPSS microspheres can 100% selectively capture Hg(II) with the coexisting of Mn(II), Co(II), Pb(II), Cd(II), Cu(II), Fe(III). And they can 100% adsorb Ag(I) with the presence of Cd(II), Pb(II), Co(II), Ni(II), and Zn(II). Moreover, the ASPSS microspheres exhibit good removal efficiency for Hg(II) and Ag(I) from simulated industrial wastewater with the coexistence of multiple pollutants. Adsorption mechanism suggests the adsorption for Hg(II) and Ag(I) is the synergistic coordination effect of amino and thiol groups. The excellent adsorption selectivity for Hg(II) and Ag(I) is attributed to the super binding ability of these functional group. ASPSS microspheres also exhibit good regeneration ability and could be reused for removing Hg (II) and Ag(I) from aqueous solution with practical value.