Abstract

A facile, one-pot reaction between 3,4,5-triamino-1,2,4-triazole (guanazine) and cyanogen bromide provides a new high-nitrogen example of the 3 H,9 H-bis[1,2,4]triazolo[1,5- a:5′,1′- d][1,3,5]triazinium system, the 2,3,5,6-tetraamino-9-imino derivative ( 3) as a quaternary bromide salt.

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