Facile adsorption-electroflotation method for the removal of heavy metal ions from water using carbon nanomaterials.

Abstract

Due to the none-biodegradable and carcinogenic nature of toxic metal ions, a novel sorption-electroflotation method was developed using carbon nanomaterials. The metal ions removed were Ni(II), Co(II), Zn(II), Fe(II), and Cu(II) using carbon nanotubes (CNTs) and carbon nanoshells (CNSs). The porous structure, morphology, composition, and surface properties of carbon nanomaterials, viz. the presence and number of functional groups are characterized by methods of low-temperature nitrogen adsorption, scanning electron microscopy, Boem, X-ray photoelectron spectroscopy. The surface of the materials was rough with varied particle sizes. Regardless of the sorbed ion and the nature of the nanomaterial, the Langmuir, Temkin, Dubinin-Radushkevich, and Flory-Higgins models were applied to the data. The maximum sorption removal on CNTs were 15.0-69.0, 36.0-75.0, 33.0-72.0, 18.0-70.0, 29.0-69.0% for Fe(II), Zn(II), Co(II), Cu(II), and Ni(II) while these values on CNSs were 19.0-53, 23.0-58.0, 30.0-79.0, 12.0-46.0, and 41.0-86%. But after simultaneous sorption-electroflotation, the percentage removal was 99.0, 97.0, 95.0, 99.0, and 52% for these metal ions, indicating an excellent combination of sorption-electro flotation. The method is highly beneficial to work in varied pH ranges as sorption and electroflotation gave the best results in acidic and basic mediums. The method is very effective, efficient, and inexpensive and can be used for the removal of the reported metal ions in water.