Abstract
A series of poly(methyl methacrylate)-block-poly(perfluoroalkyl ethyl acrylate) (PMMA-b-PFAEA) with various fluorine content were employed to fabricate honeycomb ordered films via breath figure strategy. The influences of temperature, concentration, relative humidity, fluorine content on the morphology of porous films were investigated. Wetting behavior including hydrophobic property and wetting state of the films was studied. High surface roughness from the porous structure and low surface free energy from the increasing PFAEA fraction led to the enhancement of hydrophobicity. Additionally, fabrication of porous films by the mixture of PMMA and PMMA-b-PFAEA was investigated. Ordered porous film with excellent hydrophobicity and oleophobicity was obtained with only 7wt% of PMMA-b-PFAEA by simultaneous processes of breath figure mechanism and phase separation. This work facilitates our further comprehension of the mechanism of breath figure and contributes to the fabrication of porous film from fluorinated copolymers. Meanwhile, it opens a new route to prepare films possessing excellent hydrophobicity and oleophobicity with extremely low fluorine content.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
