Fabrication of nitrogen-doped BiVO4/CrFe2O4@CNTs heterojunction for enhanced photocatalytic degradation of pesticides

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Fabrication of nitrogen-doped BiVO4/CrFe2O4@CNTs heterojunction for enhanced photocatalytic degradation of pesticides

ReferencesShowing 10 of 48 papers
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Radiation shielding, photoluminescence and antimicrobial properties of Magnesium ferrite synthesized [formula omitted] low temperature solution combustion method
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Heterostructured transition metal chalcogenides photocatalysts for organic contaminants degradation
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Photocatalytic Polyaromatic hydrocarbons (PAH) utilizing magnetic CrFe2O4 nanoparticle: Green synthesis, characterization, ab initio studies, electronic, magnetic features and water treatment application
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Evaluating the photocatalytic efficiency of the BiVO4/rGO photocatalyst
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CdS supported on electrochemically reduced rGO for photo reduction of water to hydrogen
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  • Dec 1, 1995
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  • Zhao Mengyue + 2 more

This paper studies the feasibility of photocatalytic degradation of organophosphorus pesticides using thin films of TiO2. The results show that 0·65 × 10−4mol dn−3 of dichlorvos, monocrotophos, phorate, parathion can be completely photocatalytically degraded into PO within a short time under illumination with a medium pressure mercury lamp of 375 W. The effect of parameters such as he amount of TiO2 attached, initial concentration of organphosphorus pesticides, initial pH, amount of air flow, concentrations of H2O2 and Fe3+ on the photocatalytic degradation are studied. The possible mechanisms of photocatalytic degradation are discussed. It is our assumption that the degradation reactions occur on the surface of TiO2 via primary produced oxidizing species such as the OH radical and O, after 80 h illumination, there is no significant loss of the photocatalytic activity of TiO2.

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  • Noluvuyo Mngcutsha + 4 more

The extensive use of organochlorine pesticides (OCPs) has led to significant environmental and health concerns due to their persistence, bioaccumulation, and toxicity. This study investigated the degradation of endrin pesticide using a UV-based iron oxide (Fe3O4) photocatalytic system. Prior, Fe3O4 nanocatalyst was synthesized via co-precipitation and characterized by Fourier transformed infrared spectrophotometer (FTIR), scanning electron microscope with electron diffraction spectroscope (SEM–EDX), ultraviolet spectrophotometer (UV–visible), photoluminescence (PL), and X-ray diffraction (XRD). FTIR showed a Fe–O vibrational peak at 450 cm−1, and SEM revealed irregular spherical-shaped agglomeration, confirming the successful synthesis of iron oxide nanocatalyst. Batch photocatalytic degradation of endrin in aqueous solution using a UV-H2O2-Fe3O4 nanocatalyst-based system achieved 97.87% degradation efficiency, demonstrating its potential as an effective method for removing persistent OCPs from contaminated water. Kinetic studies followed pseudo-first-order kinetics with a R 2 value of 0.9533. Cytotoxicity assessment with HepG2 cells indicated that only one sample (compound 2) exceeded a 10% cytotoxicity value, indicating potential hazardous effects on mammalian cells. The other three samples (compounds 1, 2, And 3) displayed 0% cytotoxicity, demonstrating no toxicity. These findings highlight the effectiveness of photocatalytic degradation in treating pesticide-contaminated water, contributing to the development of efficient and environmentally friendly methods, thereby reducing the detrimental impacts of OCPs on human health and ecosystems.

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