Abstract
AbstractExtensive randomization of the substituents is found in mono‐ and disubstituted diphenylacetylenes under electron impact conditions. The study of diphenylacetylenes with a variety of substituents indicates that the electron‐withdrawing groups favour the substituent scrambling, AH the substituted diphenylacetylenes give an ion at m/z 176, having a common ion‐structure, arising as a result of the expulsion of a hydrogen radical and the substituent in monosubstituted diphenylacetylenes and the expulsion of both the substituents in disubstituted diphenylacetylenes. A ring‐expanded structure is postulated for this common fragment.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
