Explosion behavior of hybrid mixtures

Analysis of the explosion behaviour of wheat starch/pyrolysis gases hybrid mixtures through experimentation and CFD-DPM simulations

Dust explosions: Emerging/unique scenarios

Effect of multi-component gaseous fuel on the explosion behaviors and mechanism of aluminum dust

It studied the explosion propagation of the hybrid mixture of LDPE dust and a small amount of ethylene (below its LEL) in a closed duct, to examine the impacts of dust concentration, dust particle size, and ethylene concentration on flame propagation behavior and overpressure characteristics. The dust concentration affected the explosion behavior of the LDPE dust/ethylene hybrid mixture in two ways. The flame gradually became discrete and unstable as the dust concentration increased, while the maximum and average flame propagation velocity, Pmax, and (dp/dt)max increased first and then decreased. The dust particle size and ethylene concentration had a significant effect on the hybrid mixture explosion. As the particle size decreased or the ethylene concentration increased, the discrete flames quickly merged into a bright continuous flame. Further, the maximum and average flame propagation velocity, Pmax, and (dp/dt)max increased, whereas the fluctuation degree of the flame propagation velocity with time showed a decreasing trend. There was no obvious agglomeration phenomenon among small LDPE particles. The explosion overpressure and flame propagation showed a strong synergistic effect. Compared with the semi-open duct, the closed duct with a more uniform dust/gas hybrid mixture showed a more continuous flame structure, a shorter flame propagation distance, and a lower flame propagation velocity. These conclusions can provide a scientific basis for explosion risk analyses and process safety designs involving the production of LDPE powder.

Explosion characteristics of three component hybrid mixtures

Investigation of the minimum ignition temperature and lower explosion limit of multi-components hybrid mixtures in the Godbert-Greenwald furnace

Explosions of methane/air/nanoparticles mixtures: Comparison between carbon black and inert particles

Study of the severity of hybrid mixture explosions and comparison to pure dust–air and vapour–air explosions

Explosions of vapour/dust hybrid mixtures: A particular class

This paper explores the explosion characteristics of three nontraditional dusts: nanomaterials, flocculent materials, and hybrid mixtures. Nanomaterials have a high likelihood of explosion with minimum ignition energies potentially less than 1 mJ. These low ignition energies may therefore allow nanomaterials to ignite due to electrostatic sparks, collision, or mechanical friction. The severity of nanomaterial explosions is affected by agglomeration and coagulation of the particles. Flocculent materials with a high length-to-diameter ratio exhibit explosion behavior patterns similar to those for spherical dusts. The length of flocculent particles plays a role in explosion likelihood which is not yet fully understood. High voltage discharge during the electrostatic flocking process is a common flocculent ignition hazard. Hybrid mixtures of a combustible dust and a flammable gas/vapor display a higher explosion severity and a lower minimum explosible concentration than that of the dust alone. Violent hybrid explosions may occur even if the dust and the gas/vapor are below their respective lean limit concentrations. 2012 American Chemical Society.

Nanoparticles are widely used in industrial applications as additives to modify materials properties such as resistance, surface, rheology or UV-radiation. As a consequence, the quantification and characterization of nanoparticles have become almost compulsory, including the understanding of the risks associated to their use. Since a few years ago, several studies of dust explosion properties involving nano-sized powder have been published. During the production and industrial use of nanoparticles, simultaneous presence of gas / vapor / solvents and dispersed nanoparticles mixtures might be obtained, increasing the risk of a hybrid mixture explosion. The aim of this work is to study the severity of the explosion of carbon black nanoparticles/methane mixtures and understand the influence of adding nanopowders on the behavior of the gas explosions. These results are also useful to understand the influence of soot on the efficiency of the gas combustion. Two grades of carbon black nanoparticles (ranging from 20 to 300 nm average diameter) have been mixed with methane. Tests have been performed on these mixtures in a standard 20 L explosion sphere. Regarding the scale precision, the lowest concentration of carbon black nanoparticles was set at 0.5 g.m-3. Tests were also performed at 2.5 g.m-3, which is still far below 60 g.m-3, the minimum explosive concentration of such powders previously determined in our laboratory. The influence of carbon black particles on the severity of the explosions has been compared to that of pure gas. It appears that the use of carbon black nanoparticles increases the explosion overpressure for lean methane mixtures at low initial turbulences by c. 10%. Similar results were obtained for high initial turbulent systems. Therefore, it seems that carbon black nanoparticles have an impact on the severity of the explosion even for quiescent systems, as opposed to systems involving micro-sized powders that require dispersion at high turbulence levels. Concerning the increment in the maximum rate of pressure rise, the addition of carbon black nanoparticles increased it by a factor of 1.15 in the case of lean fuel mixture. However, this behavior is only observed at high initial turbulence levels. The increment on the maximum rate of pressure rise is higher for powders with lower elementary particle diameter, which is notably due to the fragmentation phenomena that promotes the heat exchange.

Explosions of hybrid mixtures of methane and nicotinic acid are investigated near the lower-flammability-limit conditions. The effect on the maximum pressure and deflagration index of the ignition energy and, then, of the ignition source in combination with the turbulence is analyzed. In correspondence of limit conditions for pure methane and pure nicotinic acid, the variation of both the ignition energy and the turbulence was found to affect the behavior of the explosion. It was observed that the deflagration index is determined to be independent from the ignition energy, even though the dependence on the turbulence still remains.

Explosion of lycopodium-nicotinic acid–methane complex hybrid mixtures

96/00961 Ignition behaviour of hybrid mixtures of coal dust, methane, and air