Abstract

Abstract The mobility of the 3 P ground state of N + in helium has been calculated using the three-temperature theory of ion transport. The relevant adiabatic interaction potentials of the HeN + species have been calculated at the MP4SDQ/6-311G + (3df, 3pd) level of theory. Two limiting methods for calculating the mobility of an atomic ion in an atomic gas with orbital angular momentum greater than zero are developed and discussed.

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