Experimental Analysis on Desalinization of Brackish Water by Reverse Osmosis

Desalination of brackish water by nanofiltration and reverse osmosis

Both brackish water desalination and seawater desalination processes are well established and in common use around the globe to create new water supply sources. The farther the location of the source water from the ocean or seashore, the lower the salinity (TDS) of the water and the lower the osmotic pressure that needs to be overcome when desalinated water is produced. This is one of the major reasons that brackish desalination is often considered less costly than seawater desalination. A number of project considerations, however, indicate that seawater desalination can be beneficial and more cost-effective than brackish water desalination. To make a fair comparison, we need to properly compare all major aspects of both types of projects to define the best and most appropriate desalination technology. While brackish water has less feed water TDS, it is more challenging to dispose of the produced concentrate. Also, although brackish water desalination needs less energy to overcome osmotic pressure, it usually requires more energy to draw the water from the well than it takes to pump seawater from the open ocean intake. Another factor is that the temperature of the brackish well water may be lower than the temperature of ocean water, giving seawater desalination an advantage in energy demand. In comparing brackish to seawater desalination, these major aspects should be evaluated: (1) Locations of seawater and brackish water plants, relative to the major consumers of the desalinated water, (2) Transportation (pumping and disposal) costs of the feed water and produced water, (3) Potential colocation of a seawater plant with a large industrial user (e.g., power plant) of the seawater for cooling or other purposes, (4) Produced quality of brackish water and seawater desalination in terms of major minerals and emerging contaminants, (5) Sustainability of the water source: capacity and depth of the brackish water wells, as well as the type of soil. (6) Technical and economic aspects of produced concentrate disposal, (7) Permitting process costs for brackish and seawater desalination, and (8) The economics of both brackish and seawater desalination treatment processes: capital costs, operational and maintenance (O&M) costs, lifetime water cost, and total water cost (TWC). This paper discusses the major evaluation criteria and considerations involved in properly comparing the economic and technical aspects of brackish and seawater desalination to determine the more favorable desalination technology for a given desalination project.

Analysis of desalination alternates for phosphoric acid plant in Tunisia

We are continually inundated with news and views about the demand for water outpacing supply. Our unsustainable development along rivers that do not reach the sea, declining ground water levels, damage to wetlands, high costs associated with acquiring new sources of water, and potential shortages related to global climate change are common news items. In most developed economies, there is little or no unallocated fresh water left to exploit. So, the question becomes: Where do we find “new” water for our burgeoning population? The answer may lie in the treatment of both shallow, brackish ground water and postconsumer water. Recent advances in reverse-osmosis membranes have reduced operational costs and established a linear correlation between total dissolved solids and operational cost of desalination; thus, there is increased interest in brackish water as input source. In the Southwest, the El Paso, Texas, Water Utilities Public Service Board recently dedicated a 100 million L/d desalination plant. Surprisingly, Florida with its high rainfall of more than 100 cm a year and many lakes and rivers is commonly thought of as a water-“rich” state; yet it has more water desalination plants than any other state: the city of Tampa Bay has the largest active desalination plant in the United States and uses brackish water from Tampa Bay. It is estimated that the state of New Mexico contains 16,000 billion m3 (13 billion acre-feet) of shallow brackish ground water (total dissolved solids greater than 500 mg/L and less than sea water, which is 35,000 mg/L). I suspect that development of brackish water aquifers would, in general, have less impact on the ecology than development of fresh water aquifers. That being said, we know little about the extent and chemistry of brackish water aquifers and almost nothing about their boundary conditions. Thus, I propose a federal 10-year sunset assessment of 1‰ per 250 gallons on all the ground water that municipalities extract, or about $1.00 each year for the average household using ground water. It is envisioned that this study would quantify the regional hydrology of these aquifers following the USGS’s Regional Aquifer System-Analysis model for fresh water aquifers. It would also identify any potential deeper formations capable of sequestering desalination concentrate. This small investment coupled with reduced consumption from increased rate changes and conservation measures such as low-flush toilets, low-flow showerheads and watering restrictions will prolong our existing resources and give us time to install the necessary infrastructure. We need to wean ourselves from our “once through, throw it out” philosophy that dominates current water resource management. We also need to reframe the linguistic argument away from “sewerage” or “waste water” toward the more societally acceptable “postconsumer” or “surplus municipal water.” (Remember, it is not a “used” car, it is a “previously owned” car!) Cities will soon no longer have the luxury of passing their used municipal water downstream. “Dilution is the solution to pollution” is a dated and unfair concept of passing water quality problems to the aquatic environment and cleanup expenditures to downstream users. Newly engineered membranes in desalination plants are excellent at removing not only salts but also pharmaceuticals, endocrine disruptors, prions, and other undesirable products left untouched by conventional waste treatment facilities. Combining membrane-treated water with aquifer storage and recovery (ASR) offers some interesting water management possibilities. That is, by recharging refreshed water, which is generally of better quality than native ground water, into aquifers, one can control the blending ratio of refreshed to native ground water in producing well fields. Furthermore, the aquifer provides a unique environment to adjust the temperature and chemistry and continue filtering the recharged water, adding insurance against the transport of many undesirable contaminants. Desalination and ASR are, however, energy-intensive processes; thus, greenhouse gas–free energy is likely to be integrated in any future energy scenario. Currently, approximately 28% of all electrical power generated in the United States is greenhouse gas–free (nuclear 19.3%, hydro 6.5%, biofuels 1.6%, wind less than 1%, and solar less than 1%), so these are likely to be the energy sources for desalination. Because both the membrane and the ASR technologies are mature and well established, development of new water from brackish ground water and postconsumer water could be a rapid and straightforward resolution to many of the domestic and industrial demands of our nation’s water resources well into the future.

This article deals with the desalination of seawater and brackish water, which can deal with the problem of water scarcity that threatens certain countries in the world; it is now possible to meet the demand for drinking water. Currently, among the various desalination processes, the reverse osmosis technique is the most used. Electrical energy consumption is the most attractive factor in the cost of operating seawater by reverse osmosis in desalination plants. Desalination of water by solar energy can be considered as a very important drinking water alternative. For determining the electrical energy consumption of a single reverse osmosis module, we used the System Advisor Model (SAM) to determine the technical characteristics and costs of a parabolic cylindrical installation and Reverse Osmosis System Analysis (ROSA) to obtain the electrical power of a single reverse osmosis module. The electrical power of a single module is 4101 KW; this is consistent with the manufacturer's data that this power must be between 3900 kW and 4300 KW. Thus, the energy consumption of the system is 4.92 KWh/m3.Thermal power produced by the solar cylindro-parabolic field during the month of May has the maximum that is 208MWth, and the minimum value during the month of April, which equals 6 MWth. Electrical power produced by the plant varied between 47MWe, and 23.8MWe. The maximum energy was generated during the month of July (1900 MWh) with the maximum energy stored (118 MWh).

Brackish water desalination using reverse osmosis and capacitive deionization at the water-energy nexus

A nanofibrous composite reverse osmosis (RO) membrane with a polyamide barrier layer containing interfacial water channels was fabricated on an electrospun nanofibrous substrate via an interfacial polymerization process. The RO membrane was employed for desalination of brackish water and exhibited enhanced permeation flux as well as rejection ratio. Nanocellulose was prepared by sequential oxidations of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and sodium periodate systems and surface grafting with different alkyl groups including octyl, decanyl, dodecanyl, tetradecanyl, cetyl, and octadecanyl groups. The chemical structure of the modified nanocellulose was verified subsequently by Fourier transform infrared (FTIR), thermal gravimetric analysis (TGA), and solid NMR measurements. Two monomers, trimesoyl chloride (TMC) and m-phenylenediamine (MPD), were employed to prepare a cross-linked polyamide matrix, i.e., the barrier layer of the RO membrane, which integrated with the alkyl groups-grafted nanocellulose to build up interfacial water channels via interfacial polymerization. The top and cross-sectional morphologies of the composite barrier layer were observed by means of scanning electron microscopy (SEM), atomic force microscopy (AFM), and transmission electron microscopy (TEM) to verify the integration structure of the nanofibrous composite containing water channels. The aggregation and distribution of water molecules in the nanofibrous composite RO membrane verified the existence of water channels, demonstrated by molecular dynamics (MD) simulations. The desalination performance of the nanofibrous composite RO membrane was conducted and compared with that of commercially available RO membranes in the processing of brackish water, where 3 times higher permeation flux and 99.1% rejection ratio against NaCl were accomplished. This indicated that the engineering of interfacial water channels in the barrier layer could substantially increase the permeation flux of the nanofibrous composite membrane while retaining the high rejection ratio as well, i.e., to break through the trade-off between permeation flux and rejection ratio. Antifouling properties, chlorine resistance, and long-term desalination performance were also demonstrated to evaluate the potential applications of the nanofibrous composite RO membrane; remarkable durability and robustness were achieved in addition to 3 times higher permeation flux and a higher rejection ratio against commercial RO membranes in brackish water desalination.

Climate change, population growth, and increased industrial activities are exacerbating freshwater scarcity and leading to increased interest in desalination of saline water. Brackish water is an attractive alternative to freshwater due to its low salinity and widespread availability in many water-scarce areas. However, partial or total desalination of brackish water is essential to reach the water quality requirements for a variety of applications. Selection of appropriate technology requires knowledge and understanding of the operational principles, capabilities, and limitations of the available desalination processes. Proper combination of feedwater technology improves the energy efficiency of desalination. In this article, we focus on pressure-driven and electro-driven membrane desalination processes. We review the principles, as well as challenges and recent improvements for reverse osmosis (RO), nanofiltration (NF), electrodialysis (ED), and membrane capacitive deionization (MCDI). RO is the dominant membrane process for large-scale desalination of brackish water with higher salinity, while ED and MCDI are energy-efficient for lower salinity ranges. Selective removal of multivalent components makes NF an excellent option for water softening. Brackish water desalination with membrane processes faces a series of challenges. Membrane fouling and scaling are the common issues associated with these processes, resulting in a reduction in their water recovery and energy efficiency. To overcome such adverse effects, many efforts have been dedicated toward development of pre-treatment steps, surface modification of membranes, use of anti-scalant, and modification of operational conditions. However, the effectiveness of these approaches depends on the fouling propensity of the feed water. In addition to the fouling and scaling, each process may face other challenges depending on their state of development and maturity. This review provides recent advances in the material, architecture, and operation of these processes that can assist in the selection and design of technologies for particular applications. The active research directions to improve the performance of these processes are also identified. The review shows that technologies that are tunable and particularly efficient for partial desalination such as ED and MCDI are increasingly competitive with traditional RO processes. Development of cost-effective ion exchange membranes with high chemical and mechanical stability can further improve the economy of desalination with electro-membrane processes and advance their future applications.

Side effects of antiscalants on biofouling of reverse osmosis membranes in brackish water desalination

Solar desalination plant for small size use in remote arid areas of South Algeria for the production of drinking water

Though electrodialysis (ED) and reverse osmosis (RO) are both mature, proven technologies for brackish water desalination, RO is currently utilized to desalinate over an order of magnitude more brackish water than ED. This large discrepancy in the adoption of each technology has yet to be thoroughly justified in the literature, particularly from the perspective of energy consumption. Hence, in this study, we performed a direct and systematic comparison of the energy consumption of RO and ED for brackish water desalination, precisely mapping out the ideal operational space of each technology for the first time. Using rigorous system-scale models for RO and ED, we determine the specific energy consumption and energy efficiency of each process over a wide range of brackish water conditions. Specifically, we investigate the effects of varying feed salinity, extent of salt removal, water recovery, and productivity to ultimately identify the operational sweet spots of each technology. By maintaining the same separation parameters (i.e., feed salinity, salt removal, water recovery) and productivity between RO and ED throughout the study, we ensure that our comparison of the technologies is valid and fair. Our results indicate that both RO and ED are capable of operating with high energy efficiency (>30%) for brackish water desalination, though for differing conditions. Particularly, we show that whereas ED excels for low feed salinities (<3 g L–1) and extents of salt removal, RO operates optimally for high salinity feeds (>5 g L–1), which require more extensive desalination. Through our in-depth energetic analysis, we provide guidance for future applications of RO and ED, emphasizing that increased implementation of ED will require significant reduction in the cost of ion-exchange membranes.

Design of a small mobile PV-driven RO water desalination plant to be deployed at the northwest coast of Egypt

Desalinated brackish water is becoming an important water source for agricultural irrigation. In Brackish water desalination, pretreatment of reverse osmosis is the key step in designing the plants to avoid membrane fouling and scaling. It is enormously important to carry out a study designed at ensuring the optimization of the pretreatment system for brackish desalination plant in order to optimize the quality of the water fed through the reverse osmosis membranes, to guarantee the highest performance and to minimize the number of shutdowns for chemical cleaning. In this paper, performance evaluation carried out for a brackish water reverse osmosis plant for agricultural application, located in Dokkala Region in Morocco. This plant showed poor performances after few months of operating and frequent shutdown. The operating pressure increased significantly and the permeate conductivity decreased surprisingly. To identify the causes for the poor performance, different investigations were carried out. Thus, the pretreatment scheme was thoroughly reviewed to find out the causes of anomalies. The problem was resolved by removing chlorination and sodium bisulfate steps from the pretreatment.

Reverse osmosis (RO) has proven to be an efficient technique for desalination of seawater, brackish water, and reclaimed wastewater. However, the performance of RO desalination is sensitive to its design parameters and operating conditions. The purpose of this study was to modeling the removal of total dissolved solids (TDS) and Rejection of different ions are reported from water of city of Bandar Abbas. The main purpose of this work was the prepared drinking water intrusion model. In this study, a design method based on a simulation technique has been developed for optimizing RO desalination systems. The design is made with the use of Hydranautics design software version 2011. In this paper main focus is on the design part with software. The desalinated water obtained from reverse osmosis at a pressure of 1.2 MPa showed rejections of approximately 88.49 % for SO4 2 −, 61.42 % for TDS, 70.34 for Cl- and 50.85 for Na+. It shows that software gives accurate design with least possible error and user friendly so world while accepted. Blended water, produced by mixing groundwater and surface, was proposed to optimize the produce drinking water with a recovery rate of 95 %. Reverse osmosis is an excellent alternative for the supply of water in Bandar Abbas.

Existing and the future planned desalination facilities in the Gaza Strip of Palestine and their socio-economic and environmental impact