Abstract
This article briefly reviews the statistical model of overlap and reports results from its first application to a fully characterized experimental chromatogram in which the numbers of detectible components, singlet peaks, doublet peaks, and triplet peaks are known. The overall agreement between these numbers and their theoretically expected values, which were predicted by the model from the relative distribution of maxima in the chromatogram, is very good. Specifically, the absolute errors between the predicted and actual numbers are all less than or equal to three.
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