Abstract

Excess molar volumes V E have been investigated from density ρ measurements using vibrating-tube digital densimeter DMA 60/602 for binary mixtures of methanol, 1-propanol, 2-propanol and 1-hexanol with ethyl acetate in the temperature range 298.15–323.15 K. Thermal expansion coefficients α and their excess values α E were evaluated. The results were analyzed and discussed in terms of dependence of V E on chain length of alkanol and position of hydroxyl group and effect of temperature.

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