Abstract
Flow microcalorimetric measurements of the excess isobaric heat capacity, and vibrating tube densimetric determinations of the excess volume were carried out over the whole concentration range for mixtures of hexan-2-ol or hexan-3-ol with n-heptane at 298.15 K. Particular attention was paid to the dilute alkanol region, where the excess heat capacity changes sign. This behavior is discussed in terms of the auto-association of the alkanol.
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