Evidence for synchronous cleavage of N-H and C-C bonds: bis(2,2¢-bipyridyl)copper(II) permanganate oxidation of cobalt(III) bound and unbound α-amino acids

Pownsamy Kannan,Kuyam Rathinavelu Sankaran

doi:10.1007/s11144-005-0265-7

Evidence for synchronous cleavage of N-H and C-C bonds: bis(2,2¢-bipyridyl)copper(II) permanganate oxidation of cobalt(III) bound and unbound α-amino acids

Pownsamy Kannan, Kuyam Rathinavelu Sankaran

https://doi.org/10.1007/s11144-005-0265-7

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Journal: Reaction Kinetics and Catalysis Letters	Publication Date: Jul 1, 2005
Citations: 1

Affiliation: Annamalai University

#Aqueous Acetic Acid Medium #Aqueous Acid Medium + Show 8 more

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Abstract

Oxidation of pentaamminecobalt(III) complexes of α-aminoacids by bis(2,2'-bipyridyl) copper(II) permanganate in 50% HOAc-50% H 2 O (v/v) aqueous acetic acid medium. This oxidation as a diagnostic tool to find out the fraction proceeding by synchronous cleavages of N-H and C-C bonds.

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