Abstract
[reaction: see text] Transient silenes that are strongly influenced by reversed Si[double bond]C bond polarization are formed upon heating of tris(trimethylsilyl)silylamides. The silenes are trapped with 2,3-dimethyl-1,3-butadiene to quantitatively yield only one of the possible diastereomers of the functionalized cyclic allylsilanes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
