Abstract
Solutions of 2,3-dimethylbutane (DMB) and cyclohexane containing a captodative solute, methylmethoxyacetate (MMA), were irradiated (continuous wave). Alkane dimeric products were analysed by capillary gas chromatography. G-yields were estimated as a function of the concentration of the captodative solute. By reaction with alkyl radicals, the captodative solute gives the free radical stabilized by the captodative effect. Combination reaction of this radical with itself or with alkyl radicals gives solute or mixed dimer which were also analysed. A large intensity effect was noticed, as was seen in the solutions of n-hexane-MMA. Dose effect was definitely rejected.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: International Journal of Radiation Applications & Instrumentation. Part C, Radiation Physics & Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
