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Abstract
The excess gibbs energy of mixing in binary mixtures of TBP in nonpolar solvents viz. bcnzene, carbon disulphide, cyclohexane, n-heptane, n–hexane, p–xylene, tetrachloromethane at temperature 303°K is studied. The excess free energy of mixing (AGA8) is in the order, n–hexane < n–heptane < benzene < cyclohexane < p–xylene < CCI4 < CS2. The results corroborate the findings obtained through evaluation of the excess correlation Factor.
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