Abstract
Soil laboratories throughout the United States have widely integrated the Mehlich-III (M-III), derived from Mehlich-I (M-I), methodologies to extract soil nutrients. However, there have been concerns regarding its precision. The University of Florida's Hastings Agricultural and Extension Center (HAEC) conducted a soil sampling during the spring of 2021. This research aimed to rigorously compare the extraction efficiencies of M-I and M-III, specifically focusing on critical soil nutrients like phosphorus (P), potassium (K), magnesium (Mg), calcium (Ca), boron (B), copper (Cu), iron (Fe), manganese (Mn), and zinc (Zn). From forty-six meticulously chosen fields, 276 composite soil samples derived from two distinct depth strata (0–15 cm and 15–50 cm) were analyzed using both methods. Our findings highlighted the superior extraction prowess of M-III, which showcased an efficiency almost threefold compared to M-I. Intriguingly, the correlation between M-I and M-III extraction efficiencies weakened with escalating soil nutrient concentrations. The coefficient of determination (r2) between M-I and M-III had a high correlation value and was statistically significant (p<0.05) for all macro- and micronutrients. We found that the correlation between M-I and M-III became more robust with an increase in sample size and a higher correlation coefficient. It is noteworthy to mention that the M-III method has the propensity to provide slightly inflated soil nutrient estimations. Since soil labs worldwide use M-III equations derived from M-I, this study proposes that soil labs reinvestigate and possibly adopt new correlation equations to estimate soil nutrients using M-III.
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