Abstract

Abstract Dehydrogenation of ethylbenzene to styrene with carbon dioxide has been investigated using various vanadia–alumina catalysts to exhibit high activity and selectivity. Redox behavior of vanadium oxide played a key role in the dehydrogenation. Among several additives, antimony oxide has been found for improving catalyst stability as well as catalytic activity to produce styrene, revealing that the addition of the antimony oxide leads to the easier redox cycle between fully oxidized and reduced vanadium species.

Full Text

Published Version
Open DOI Link

Topics from this Paper

  • Vanadia Alumina Catalysts
  • Reduced Vanadium Species
  • Antimony Oxide
  • Carbon Dioxide
  • Behavior Of Oxide
    • + Show 5 more

Create a personalized feed of these topics

Get Started

Get access to 115M+ research papers

Discover from 40M+ Open access, 2M+ Pre-prints, 9.5M Topics and 32K+ Journals.

Sign Up Now! It's FREE

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Similar Papers

Raman microprobe investigation of oxygen and carbon dioxide dissolution from bubbles in silicate glasses containing antimony oxide
  • Journal of Materials Science
  • Aug 1, 1991
Relevant
Not Relevant
An Overview on the Dehydrogenation of Alkylbenzenes with Carbon Dioxide over Supported Vanadium–Antimony Oxide Catalysts
  • Catalysis Surveys from Asia
  • Jul 11, 2007
Relevant
Not Relevant
Liquid fuel synthesis via CO2 hydrogenation by coupling homogeneous and heterogeneous catalysis
  • Chem
  • Mar 1, 2021
Relevant
Not Relevant
Utilization of carbon dioxide as soft oxidant in the dehydrogenation of ethylbenzene over supported vanadium–antimony oxide catalysts
  • Green Chem.
  • Jan 1, 2003
Relevant
Not Relevant
Highly efficient synthesis of dimethyl ether from syngas over the admixed catalyst of CuO–ZnO–Al2O3 and antimony oxide modified HZSM-5 zeolite
  • Energy Conversion and Management
  • Jun 1, 2010
Relevant
Not Relevant
Oxidation of benzothiophene by tert-butyl hydroperoxide over vanadia–alumina catalyst: An FT-IR study at the vapour–solid interface
  • Catalysis Communications
  • Jul 1, 2009
Relevant
Not Relevant
Promotional effect of sodium and phosphorus on a V-Mo-O catalyst
  • Applied Catalysis A: General
  • Apr 23, 1993
Relevant
Not Relevant
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries
  • Chem
  • Nov 1, 2020
Relevant
Not Relevant
Deactivation and oxidative regeneration of VTiSbSiOx catalyst for ammoxidation of 3-picoline to nicotinonitrile
  • Applied Catalysis A: General
  • Feb 1, 2008
Relevant
Not Relevant
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window
  • Chem
  • May 1, 2021
Relevant
Not Relevant
Catalytic oxidation of thioanisole Ph–S–CH3 over VOx/SiO2 and VOx/Al2O3 catalysts prepared by sol–gel method
  • Journal of Molecular Catalysis A: Chemical
  • Aug 1, 2006
Relevant
Not Relevant
Oxidative dehydrogenation of ethylbenzene over vanadia-alumina catalysts in the presence of nitrous oxide: structure-activity relationship
  • Journal of Catalysis
  • Mar 10, 2005
Relevant
Not Relevant
Vapour phase oxidation of acrolein to acrylic acid on mixed oxides as catalyst
  • Journal of Applied Chemistry and Biotechnology
  • Jan 1, 1977
Relevant
Not Relevant
Vapour phase oxidation of acrolein to acrylic acid on mixed oxides as catalyst
  • Journal of Biochemical Toxicology
  • Jan 1, 1977
Relevant
Not Relevant
Dehydrogenation of Ethylbenzene with Carbon Dioxide over Supported Vanadium- Antimony Oxide Catalysts: Effect of Zirconia Modification in Alumina Support
  • Bulletin of the Korean Chemical Society
  • May 1, 2006
Relevant
Not Relevant
READ MORE FROM

Catalysis Communications

Nature inspired Ficus Religiosa leaf mesh coated with antibacterial ZnO/PANi@PMMA nanocomposite for separation and water purification
Open Access
Just Published
  • Catalysis Communications
  • Dec 1, 2023
Relevant
Not Relevant
Investigating the impact of chemical structures on the photocatalytic degradation rates over ZnO nanorods: An oxidative pathways perspective
Open Access
Just Published
  • Catalysis Communications
  • Dec 1, 2023
Relevant
Not Relevant
Selective oxidation of cyclohexane over nanostructured manganese tungstate: Contribution of Mn and W related sites
Open Access
Just Published
  • Catalysis Communications
  • Dec 1, 2023
Relevant
Not Relevant
Fabrication and characterization of BiOxBry/BiOmIn coupled GCN heterojunctions with enhanced visible-light catalytic activity
Open Access
  • Catalysis Communications
  • Nov 1, 2023
Relevant
Not Relevant
Synthesis of nitrogen-doped carbon catalyst from hydrothermally carbonized wood chips for oxygen reduction
Open Access
  • Catalysis Communications
  • Nov 1, 2023
Relevant
Not Relevant
Solar photodegradation of malathion from aqueous media using Al-doped ZnO/Fe3O4 nanocomposite
Open Access
  • Catalysis Communications
  • Nov 1, 2023
Relevant
Not Relevant
Effect of Co/Ni ratio on electrocatalytic oxygen evaluation reaction of hydrothermally derived CoNi2S4 in alkaline medium
Open Access
  • Catalysis Communications
  • Nov 1, 2023
Relevant
Not Relevant
Chemobiocatalytic transformation of biomass-derived D-xylose into furfuryl alcohol in a sustainable reaction system
Open Access
  • Catalysis Communications
  • Nov 1, 2023
Relevant
Not Relevant
Green construction of magnetic MnFe2O4/ZIF-8 nanocomposite utilizing extract of Melissa officinalis plant for the photo-degradation of tetracycline under UV illumination
Open Access
  • Catalysis Communications
  • Nov 1, 2023
Relevant
Not Relevant
Facile synthesis of N-acetylglycine from chitin-derived N-acetylmonoethanolamine
Open Access
  • Catalysis Communications
  • Nov 1, 2023
Relevant
Not Relevant