Abstract
Epoxidation of fluoroallylic alcohols with VO(acac) 2 or Ti(OiPr) 4 + TBHP results in high diastereoselectivity (90–95%). Epoxidation with m-CPBA gives the erythro isomer as the major component, as opposed to the hydrocarbon series. The ring opening of epoxy alcohols by nucleophiles is easy.
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