Abstract
Abstract A catalytic amount of an oxalate/oxalic acid buffer strongly enhances the catalytic properties of Mn-tmtacn complexes for epoxidation reactions with H 2 O 2 . Especially terminal olefins are easily epoxidized. Yields for e.g. allyl acetate or 1-hexene reach up to 99% and 65% on olefin and peroxide basis respectively. The reaction is stereospecific; there are no products of solvolysis.
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