Abstract
Polymer-bound piperazine was readily prepared from Merrifield resin and was used as a robust support for immobilization of molybdenum hexacarbonyl. This polymer-supported molybdenum catalyst shows high activity in the epoxidation of various alkenes in the presence of tert-butylhydroperoxide (TBHP). This new heterogenized molybdenum catalyst can be recovered and reused for eight times without loss of its activity.
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