Environmental Remediation of Toxic Organic Pollutants Using Visible-Light-Activated Cu/La/CeO2/GO Nanocomposites.

Abstract

Environmental pollution is a major threat that increases day by day due to various activities. A wide variety of organic pollutants enter the environment due to petrochemical activities. Organic contamination can be unsafe, oncogenic, and lethal. Due to environmental issues worldwide, scientists and research communities are focusing their research efforts on this area. For the removal of toxic organic pollutants from the environment, photocatalysis-assisted degradation processes have gained more attention than other advanced oxidation processes (AOPs). In this manuscript, we report a novel photocatalysis of copper and lanthanum incorporating cerium oxide (CeO2) loaded on graphene oxide (Cu/La/CeO2/GO) nanocomposites successfully synthesized by hydrothermal techniques. XRD results showed the presence of dopant ions and a crystalline structure. FESEM images showed that the surface morphology of the synthesized nanocomposites formed a rod-like structure. The highlight of this study is the in-situ synthesis of the novel Cu/La/CeO2/GO nanocomposites, which manifest higher photodegradation of harmful organic dyes (Rhodamine B (RhB), Sunset Yellow (SY), and Cibacron Red (CR)). In Cu/La/CeO2/GO nanocomposites, the dopant materials restrict the rapid recombination of photoinduced electron–hole pairs and enhance the photocatalytic activity. The degradation percentages of RhB, SY, and CR dye solution are 80%, 60%, and 95%, respectively. In summary, the synthesized nanocomposites degrade toxic organic dyes with the help of visible light and are suitable for future industrial applications.