Enhancing tunnel muck properties with ternary industrial solid wastes: optimal mixing ratios and microscopic mechanisms

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Calcium carbide slag (CCS), phosphogypsum (PG), and red mud (RM), three types of industrial solid wastes, were employed to improve tunnel muck for assessing the feasibility of their reuse. A series of indoor tests were conducted to investigate the effects of their contents on the physical and mechanical properties of the improved tunnel muck. Microscopic tests were also conducted to reveal the improvement and interaction mechanisms involved. Results indicate that the incorporation of CCS, PG, and RM can significantly improve and enhance the physical and mechanical properties of tunnel muck. The improved tunnel muck containing 2% PG and 6% RM shows higher early strengths as CCS content exceeds 4%. However, after curing for more than 14 days, the unconfined compressive strength (UCS) of the tunnel muck with 4% PG and 4% RM is the maximum regardless of the CCS content. Microscopic analysis shows that reactive substances in industrial solid waste react chemically with soil components, exchanging ions and forming cementitious products such as calcium hydroxide, calcium silicate hydrate (C-S-H), calcium aluminosilicate hydrate (C-A-S-H), and ettringite (AFt). They bind, fill, and encapsulate soil particles, compacting the soil and significantly enhancing the physical and mechanical properties of tunnel muck. Moreover, there is a notable mutual synergy between PG and RM, primarily attributed to their acid-base neutralization and the complementary action of reactive ions. The improved tunnel muck containing 4% CCS, 4% PG, and 4% RM demonstrates the highest enhancement efficiency.