Abstract

Additions of 1–5 wt% W element enhanced corrosion resistance and mechanical properties of LDED-316 SS. Microstructure characterized the grain refinement and precipitation of ferrite and W-Mo carbides. Mechanical tests showed enhanced tensile strength and hardness of 316–5 W by 37.4% and 30.8%, respectively. Electrochemical tests indicated an increasing pitting potential and polarization resistance of 316–3 W in 3.5 wt% NaCl solution by 0.535 VSCE and 1679 kΩ·cm2, respectively. Corrosion morphology showed the preferential dissolution of ferrite and W-Mo carbides rather than austenite cell. The change in corrosion processes and presence of WO3 in the passivation film significantly contributed corrosion resistance.

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