Abstract

The achievement of compact and defect-free film structure is crucial for the application of b-oriented MFI zeolite film. In this work, a novel heat treatment technique was used to treat zeolite seeded substrates prior to secondary growth. The influence of the heat treatment parameters such as treat temperature and time on the final film morphology were systematically investigated. The relationship between film compactness and the parameters was established. Under the optimized treat temperature of 120 °C and treat time of 1 h, compact and uniform b-oriented MFI zeolite film was achieved. The applicability of the optimum heat treatment condition was validated by employing various film substrates.

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