Abstract

The novel device for measuring characteristics of the process that takes place when hydrocarbon liquids are subjected to elevated temperatures is described. The measuring cell has the form of a loop in which circulation is induced by a turbine stirrer. The stirrer contains magnets built into its blades, enabling mixing by a magnetic mixer positioned below the cell. No moving part protrudes from the cell. The fouling process takes place at the hot-wire probe positioned at the centre of the liquid stream. Thermo-graphic images of the cell with circulating liquid are used to establish the type of the flow within the cell. The tests were performed with various types of liquids and versatility of the device demonstrated.

Highlights

  • During processing, refinery hydrocarbons are heated up usually to temperatures from 250 to 550 °C

  • The magnitude of the problem appears to be highest in crude oil distillation units, so that the majority of the reports are dealing with crude oil fouling properties[4,5,6]

  • Reported fouling testing encompasses a wide variety of liquids and their specific compositions encountered in petrochemical industry

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Summary

Introduction

Refinery hydrocarbons are heated up usually to temperatures from 250 to 550 °C This causes the development of various processes resulting in a deposit adhering to the walls of the processing equipment. The fouling of process units walls diminishes the heat transfer significantly making it the major problem in the petrochemical industry[1]. When the decrease in heat transfer efficiency becomes so severe that the required temperature cannot be reached, the operation must be stopped and the equipment cleaned. This causes expenses which are quite high as has been documented in the literature[2,3]. The magnitude of the problem appears to be highest in crude oil distillation units, so that the majority of the reports are dealing with crude oil fouling properties[4,5,6]

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