Engineering cellulose aerogel composites for mercury ion sequestration and aquatic real time monitoring based on the immobilization of metal-organic frameworks.

Abstract

Industrial wastewater effluents containing elevated levels of mercury are a significant menace to both the ecosystem and human health. Despite the advent of metal-organic frameworks (MOFs) as promising adsorbents, their application in treatment of industrial wastewater has been impeded by the challenges associated with handling their powdered form. In this work, we introduce a straightforward method for fabricating MOF composite cellulose aerogels (5MM-101@CA). The resulting adsorbent showed a high adsorption capacity of 409.84 mg/g for Hg (II), with over 75 % removal efficiency maintained after five consecutive adsorption-desorption cycles. Furthermore, the material exhibited high sensitivity for the real-time detection of Hg (II), with a detection limit as low as 6.89×10-8 M. The adsorbent also showed remarkable fluorescence stability for up to a week, indicative of its excellent optical performance. Dynamic adsorption demonstrated the adsorbent's ability to sustain continuous and stable system operation without compromising adsorption efficiency. These findings underscore the effectiveness of post-synthetic modification (PSM) technology in enhancing the performance of MOFs, while highlighting the utility of low-cost cellulose as an effective carrier. Thus, the composite material developed in this work is promising as it not only maximizes the adsorption capabilities of MOFs but also circumvents the risk of secondary pollution.