Abstract
Pumice is an environmental friendliness and low-cost carrier material for development of paraffin-pumice phase change energy storage composites (PP) at low air pressure in this work. PP was incorporated into cement to obtain CBM-PP. Microstructural, chemical, and thermal characteristics of PP were investigated by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) tests. Moreover, thermal energy storage and hydrophobicity characteristics of CBM-PP were performed by thermal conductivity, drip, and water absorption experiments. Results show that paraffin is effectively impregnated into pumice pores. There exists a physical interaction between paraffin and pumice. And PP possesses excellent compatibility and thermal stability, while its phase change temperatures and thermal energy storage capacities are in the ranges of 51.84–54.69 °C and 77.22–110.60 J/g, respectively. Furthermore, CBM-PP possesses excellent thermal energy storage and hydrophobicity at low air pressure in plateau areas, thus exhibiting a good application prospect in building thermal management and impermeability. Moreover, the thermal conductivity variation of CBM-PP is studied by the thermal conductivity model, which can predict the thermal conductivity with an error of no >9 %.
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