Abstract

The ionization and differentation behavior of two groups of sphinganine analog mycotoxins (SAMs), the AAL toxins (TA, TB, TC, TD, and TE) and fumonisins (FB 1 and FB 2 ), were compared in positive and negative electrospray ionization (ESI) modes. Toxins containing amino groups yielded abundant [M+H] + in positive mode, whereas N-acetylated town congeners were protonated less efficiently but yielded abundant [M+Na] + ions. Negative ESI mass spectra exhibited abundant [M-H] - ions for all towns, and fumonisins could be distinguished by the presence of additional peaks corresponding to [M-2H] 2-

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