Abstract
Abstract Electronic spectra of hydrogen-bonded complex cations of phenol with N(CH3)3, NH3 and H2O were investigated by photodissociation spectroscopy combined with a new method for the generation of jet-cooled molecular complex ions. The method involves the ionization of phenol followed by a jet expansion for the efficient formation of the complex ions as well as for the cooling. Well-resolved vibronic bands, including the bands due to intermolecular stretching vibrations, were obtained for the complex ions of phenol with N(CH3)3 and NH3. Differences between the ionic and neutral forms of these complexes were discussed on the basis of the results.
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