Abstract
The RbPb 2Br 5 crystal has been grown by Bridgman method. The electronic structure of RbPb 2Br 5 has been measured with XPS for a powder sample. High chemical stability of RbPb 2Br 5 surface is verified by weak intensity of O 1s core level recorded by XPS and structural RHEED measurements. Chemical bonding effects have been observed by the comparative analysis of element core levels and crystal structure of RbPb 2Br 5 and several rubidium- and lead-containing bromides using binding energy difference parameters Δ Rb = (BE Rb 3d − BE Br 3d) and Δ Pb = (BE Pb 4f 7/2 − BE Br 3d).
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