Abstract
Angle-resolved ultraviolet photoelectron spectroscopy has been performed for a C 8 K single crystal. The dispersive π * -band near the \(\tilde{K}\) point and the so-called K 4s band around the Γ point are experimentally identified. The experimentally determined band structure has been compared with two different band calculations to discuss the charge transfer in C 8 K. The observed difference in the spectral feature of the `K 4s' band between the experiment and the calculation are also discussed.
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