Abstract

The mass spectrometric behaviour of seven 2a,4-disubstituted 2-phthalimido-2,2a,3,4-tetrahydro-1H-azeto[2,1-d][1, 5]benzothiazepin-1-ones has been studied with the aid of mass-analyzed ion kinetic energy spectrometry and accurate mass measurements under electron impact ionization. All compounds show a tendency to eliminate a CO molecule, a phthalimido (PhthN) radical, or a phthalimide (PhthNH) molecule. All of the resulting fragment ions could further lose a propene or (substituted) styrene molecule. The molecular ions could also undergo a reverse [2 + 2] cycloaddition reaction.

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