Abstract

The effect of electron correlation on bond alternation of polymers is clarified by calculation of the electron correlation function. Instead of the extended Hubbard model, we start from the full Coulomb interaction with any strength and range. In contrast to the other theories, our results disclose the following: (1) When the interaction range is short the bond alternation monotonically decreases with increasing strength. (2) Extension of the interaction range will increase bond alternation. (3) If the electron-lattice coupling is strong, bond alternation is suppressed by electron repulsion; but if it is weak the bond alternation is mainly caused by repulsion.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.