Abstract

Ni–B4C composite coatings on carbon steel substrates with various contents of B4C nano-particulates were prepared by electrodeposition in Ni plating bath containing B4C nano-particulates. Microhardness, Scanning Electron Microscopy (SEM), Tafel polarization and Electrochemical Impedance Spectroscopy (EIS) measurements were used to compare pure nickel coatings and Ni–B4C composite coatings. Pure Ni coating microhardness is lower than that of Ni–B4C coatings and the microhardness of the composite coatings increases with the increase of the content of B4C nano-particulates. The effects of various contents of B4C nano-particulates on the corrosion resistance were investigated and it was found that the best anti–corrosion property of Ni–B4C composite coatings is at 6 g/L B4C in the bath formulation.

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