Abstract

A series of carbon aerogels (C-AGs) were prepared by the pyrolysis of resorcinol-formaldehyde aerogels at 700–1100 °C as potential supercapacitor electrodes, and their texture and electrochemical properties were determined. The specific surface area of all C-AGs was in the range of 700–760 m2/g, their electron conductivity increased linearly from 0.4 to 4.46 S/cm with an increase of the pyrolysis temperature. The specific capacitance of electrode material based on C-AGs reached 100 F/g in sulfuric acid and could be realized at a 2 A/g charge-discharge current, which makes it possible to use carbon aerogels as electrode materials.

Highlights

  • In recent years, new carbon materials have attracted increased attention due to their excellent properties

  • A standard resorcinol:formaldehyde 1:2 molar ratio was applied in all cases

  • 1.47 mL (0.02 mol) of formaldehyde solution were added, and the mixture was stirred for 10–20 min

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Summary

Introduction

New carbon materials have attracted increased attention due to their excellent properties. One of the promising materials is carbon aerogel (C-AGs), which is a 3D-network of nanoscale particles. Such materials are usually synthesized by the pyrolysis of precursors, such as polymer organic aerogels [1]. The use of C-AGs as an electrode material in electrochemical double-layer capacitors (supercapacitors) has been described in a number of works [9,10,11,12,13,14,15,16]. Silicon carbide aerogels were treated with chlorine gas at 700–1000 ◦ C to remove silicon and to form a highly porous carbon material with a specific surface area as high as 2700 m2 /g. Similar material prepared by high-temperature chlorination of molybdenum carbide provided a ~125 F/g gravimetric capacitance value [15]

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