Abstract
The cathodic polarograms and cyclic voltammograms for Ru(døphen)32+ (døphen=4,7-diphenyl-1, 10-phenanthroline), Fe(TPTZ)22+ (TPTZ=2,4,6-tri(2-pyridyl)-1,3,5-triazine), Ru(TPTZ)22+, Fe(ADPTZ)22+ (ADPTZ=2-amino-4,6-di(2-pyridyl)-1,3,5-triazine) in N,N-dimethylformamide are reported. They exhibit two sets of two or three neighbouring reversible one-electron waves. The number of the neighbouring waves within a set is equal to the number of coordinated ligand molecules. This finding suggests that the ligand molecules such as døphen, TPTZ and ADPTZ can exist as dianions when they are coordinated to a metal ion.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
