Abstract
An electrochemical approach for the indirect oxidative generation of hypervalent iodoarene as a reaction catalyst has been reported. The reaction proceeds first from the generation of active Cl species by electro-oxidation, followed by oxidative transfer to generate ArICl2, which subsequently reacts with enynes to achieve cyclization. This protocol provides a simple and green method for accessing dichlorinative cyclization products in high yields with good selectivity.
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