Abstract
As a result of the toxic and corrosive nature of chlorine gas, simple methods for its detection are required for monitoring and control purposes. In this paper, the electrochemical behavior of chlorine on platinum working electrodes in the room temperature ionic liquid (RTIL) 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C2mim][NTf2]) is reported, as a basis for simple sensor devices. Cyclic voltammetry (CV) and chronoamperometry (CA) on a Pt microelectrode revealed the two-electron reduction of Cl2 to chloride ions. On the CV reverse sweep, an oxidation peak due to the oxidation of chloride was observed. The reduction process was diffusion controlled at the concentrations studied (≤4.5% in the gas phase), in contrast to a previous report (J. Phys. Chem. C 2008, 112, 19477), which examined only 100% chlorine. The diffusion-controlled currents were linear with gas-phase concentration. Fitting of the CA transients to the Shoup and Szabo expression gave a diffusion coefficient for chlorine ...
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