Abstract

The electrical properties of some charge transfer complexes, with stoichiometries 1:1 and 1:2 (donor : acceptor), of 1,5-diaminonaphthalene and 2,3-diaminonaphthalene with dinitro- and trinitrobenzenes have been investigated. The positive temperature coefficient of electrical conductivity (dσ/d T) is evidence for a semiconducting character. The energy gaps ( E g) for conduction and the charge transfer excitation energies ( E CT) have been discussed. The mechanism of the conduction process is also interpreted.

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