Abstract
The electrical and optical properties (dipole moment, electrooptical and optical Kerr constants, molecular polarizability anisotropy, polarizability tensor, molecular refraction) of N,N-dimethylnitramine as the simplest N NO 2 derivative were studied by a set of experimental and theoretical methods with the aim to determine the components of the polarizability ellipsoid of the N NO 2 group and develop a valence-optical scheme for calculating the optical and electrooptical parameters of N NO 2 compounds. Conjugation of the p electrons of the imide nitrogen atom with the electrons of the nitro group results in deviation of the proper- ties of N,N-dimethylnitramine from the additive values. Comparative evaluation of the parameters of the C sp 3 NO 2 ,C sp 2 NO 2 , and N NO 2 groups was made.
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