Abstract

The Li, Ta, and Sb modified (Na,K)NbO3 ceramics were reported to exhibit excellent piezoelectric properties typically in the vicinity of orthorhombic (O) and tetragonal (T) phase boundaries. Ex- and in-situ synchrotron x-ray diffraction measurements have provided a direct evidence of the electric-field induced phase instability owing to reversible phase transition between monoclinic (Mc) phase and T phase. A low-symmetry Mc phase was irreversibly produced from the initial O phase after the electric field was applied. Experimental results suggested that the Mc-T phase coexistence and reversible Mc-T phase transition (phase instability) may be responsible for enhanced piezoelectric activity in these compositions.

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