Abstract

A modified van der Waals model is used to describe the effect of a time-varying external electric field on the critical mixing-point properties of a dipolar binary mixture. Assuming that the behavior of the concentration fluctuations about equilibrium is governed by linearized hydrodynamic equations and that the diffusion coefficient is determined by the instantaneous equilibrium state, the decay of the fluctuations is described. The relaxation time characterizing the electric field effect upon the light scattering by critical opalescence is related to the free relaxation of the concentration fluctuations.

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