Abstract

Environmental variables such as temperature, matric suction and pore fluid composition are well known to influence the hydro-mechanical behavior of clays and shales. The type and the relevance of this influence depends on the mineralogical composition and on the fabric of the material. Soil activity is an engineering proxy for mineralogical composition which can be used for a preliminary characterization of the expected type of behaviour under chemical actions, if those do not imply very significant cation exchange or pH variations. Very large chemo-mechanical effects occur in highly active soils used in engineering works such as barriers for nuclear waste or landfills, however concentration changes also impact on the mechanical behavior of non – active soils and rocks, such as illitic or natural blends of clays. Such materials are widely distributed in nature and their mechanical response upon chemical changes can be problematic in many cases. Examples of engineering relevance include vast slope instabilities promoted by fabric changes due to desalinization in Scandinavian quick clays, and instability or convergence issues for boreholes drilled in shales exposed to muds with a different chemical composition from the one of the pore fluid. An elastoplastic model is formulated to simulate the volumetric behaviour of such materials along chemical and mechanical loads. In addition to the parameters of the Modified Cam Clay, it requires defining the dependency of the elasto-plastic compliance and reference void ratio on pore fluid salinity. The model performs well against experiments from literature where complex chemo-mechanical histories were imposed.

Highlights

  • The dependency of the mechanical response of soils with a significant clay fraction on the chemical composition of the pore fluid is well known in the scientific literature

  • Examples of engineering relevance include vast slope instabilities promoted by fabric changes due to desalinization in Scandinavian quick clays, and instability or convergence issues for boreholes drilled in shales exposed to muds with a different chemical composition from the one of the pore fluid

  • Other factors linked to the mineralogy play an important role, e.g. (i) pH controls the superficial charge of kaolinite; (ii) the size and charge of the cation in the pore fluid controls the effectiveness of the bonds between different mineral layers in montmorillonite minerals

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Summary

Introduction

The dependency of the mechanical response of soils with a significant clay fraction on the chemical composition of the pore fluid is well known in the scientific literature. The pore fluid salinity only has a small influence on the compression behaviour of normal or inactive soils, such as kaolinite [6], illite [7, 8] and natural clays of mixed composition [9, 10]. These soils still develop important volume strains when exposed to salinity changes under constant stress [8 ,10]. After describing model assumptions and equations, numerical predictions are compared to experimental results for two different non - active clays from the literature

Stress variables
Elastic behaviour
Isotropic paths
Axis symmetric paths
Simulation of chemo-mechanical tests from the literature
Mechanical test with osmotic suction increase under constant stress
Mechanical test with osmotic suction decrease under constant stress
Conclusions
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