Abstract
Electron elastic scattering total cross sections (TCSs) for Y, Ru, Pd, Ag and Pt atoms are investigated in the electron impact energy range 0 ⩽ E ⩽ 7.0 eV. The complex angular momentum method that incorporates the electron–electron correlations and core-polarization interactions, crucial for the existence and stability of most negative ions, is used for the calculations. The TCSs for these atoms are found to be characterized by shape resonances (short-lived resonances), Ramsauer–Townsend minima and very sharp resonances (long-lived resonances) that correspond to the existence of stable bound states of the negative ions formed during the collision as Regge resonances. Using the configuration of the negative-ion resonances and Ramsauer–Townsend minima in the Au TCS as the benchmark for nanocatalysts, we conclude that the Y, Ru, Pd, Ag and Pt atoms represent excellent candidates for nanocatalysts individually or in various combinations. Calculated electron elastic TCSs for Y, Ru, Pd, Ag and Pt atoms are presented as illustrations.
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More From: Journal of Physics B: Atomic, Molecular and Optical Physics
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