Abstract
ABSTRACTMultilayer bulk heterojunction photovoltaic cells using chlorotricarbonyl rhenium (I) bis(phenylimino)acenaphthene (Re-DIAN) complex as photosensitizer were studied. The complex is sublimable, has lower band gap, good thermal stability and good processibility. It has broad absorption in UV-visible region. Therefore, Re-DIAN exhibits good photosensitising property for photovoltaic cells. Multilayer bulk heterojunction photovoltaic cells with simple structures were fabricated base on Re-DIAN complex. The active layer consists of a blend of Re-DIAN and fullerene that were co-deposited in the same layer by vacuum deposition. The photovoltaic properties of the devices were studied by irradiaton under AM1.5 simulated solar light. The effects of changing the co-deposition film thickness, amount of Re-DIAN photosensitizer, and hole transporting materials were studied.
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