Abstract
Cu(In,Ga)Se 2 thin films have been prepared by electrodeposition from chloride electrolytes using sodium sulfamate as a complexing agent. Cyclic voltammograms indicate that sodium sulfamate can inhibit the reduction of Cu 2+, Cu + and H 2SeO 3, and accordingly hinder the formation of copper selenides. EDS analysis reveals that with the increase of sodium sulfamate concentration in the bath, atom ratio (Cu + Se)/(In + Ga) decreases while gallium content increases, and the film composition transforms from Cu-rich to Cu-poor. SEM and Raman spectra also show that copper selenides phases in electrodeposited films diminish with the increase of sodium sulfamate concentration.
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